A Structurally Diverse Series of Aluminum Chloride Alkoxides [ClxAl(m-OR)y]n (R = nBu, cHex, Ph, 2.4-tBu2C6H3)
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F09%3A00029642" target="_blank" >RIV/00216224:14310/09:00029642 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
A Structurally Diverse Series of Aluminum Chloride Alkoxides [ClxAl(m-OR)y]n (R = nBu, cHex, Ph, 2.4-tBu2C6H3)
Original language description
A diverse series of aluminum chloride alkoxides, [ClxAl(m-OR)y]n (R=nBu, cHex, Ph, 2,4-tBu2C6H3), was synthesized using the reactions of dichlorethylalane (EtAlCl2) with cyclohexanol (cHexOH), n-butanol (nBuOH), and phenols (PhOH and 2,4-tBu2C6H3OH). Eight molecular products were isolated and structurally characterized. The dimeric [Cl2Al(m- OcHex)2AlCl2] (1) was the smallest oligomer isolated among the cyclohexanolate derivatives. The adduct of 1 with cyclohexanol is a dinuclear molecule [Cl2(HOcHex)Al(m-OcHex)2AlCl2] (2) which represents a possible intermediate in the conversion reaction leading to the formation of a trinuclear bicyclic [ClAl{(m-OcHex)2AlCl2}2] (3). Two polymorphic forms of 3 were isolated. Further coordination of cyclohexanol to theLewis acidic five-coordinate aluminum atom in 3 provided [Cl(HOcHex)Al{(m-OcHex)2AlCl2}2] (4) with octahedrally coordinated central aluminum. Compound 4 could be regarded as a precursor to the well-known Mitsubishi (tridiamond) tetranucl
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA203%2F08%2F1111" target="_blank" >GA203/08/1111: Synthesis and properties of inorganic-organic polymeric materials</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2009
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
INORGANIC CHEMISTRY
ISSN
0020-1669
e-ISSN
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Volume of the periodical
48
Issue of the periodical within the volume
17
Country of publishing house
US - UNITED STATES
Number of pages
9
Pages from-to
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UT code for WoS article
000269313500014
EID of the result in the Scopus database
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