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Laser desorption ionization time-of-flight mass spectrometric study of binary As-Se glasses

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F10%3A00044798" target="_blank" >RIV/00216224:14310/10:00044798 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216275:25310/10:39881358

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Laser desorption ionization time-of-flight mass spectrometric study of binary As-Se glasses

  • Original language description

    Binary chalcogenide As-Se glasses are important for optics, computers, material science and technological applications but the structure is still not completely known. The formation of clusters in a plasma plume from different glasses by laser desorptionionization (LDI) or laser ablation (LA) was studied by time-of-flight mass spectrometry (TOF MS) in positive and negative ion modes. Formation of a number of AspSeq singly charged clusters As3Seq+ (q = 1-5), AsSeq- (q = 1-3), As2Seq- (q = 2-4), and As3Seq- (q = 2-5) was found from As-Se glasses with the molar ratio As:Se equal to 0.5 to 2.3. The stoichiometry of the AspSeq clusters was determined via isotopic envelope analysis and computer modeling. The structure of the clusters is proposed and the relation to the structure of the glasses is discussed.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CB - Analytical chemistry, separation

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2010

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Rapid Communications in Mass Spectrometry

  • ISSN

    0951-4198

  • e-ISSN

  • Volume of the periodical

    24

  • Issue of the periodical within the volume

    24, 2010

  • Country of publishing house

    CZ - CZECH REPUBLIC

  • Number of pages

    2008

  • Pages from-to

  • UT code for WoS article

  • EID of the result in the Scopus database