Anion-Free Bambus[6]uril and Its Supramolecular Properties
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F11%3A00049823" target="_blank" >RIV/00216224:14310/11:00049823 - isvavai.cz</a>
Alternative codes found
RIV/68378271:_____/11:00366974
Result on the web
<a href="http://onlinelibrary.wiley.com/doi/10.1002/chem.201003683/pdf" target="_blank" >http://onlinelibrary.wiley.com/doi/10.1002/chem.201003683/pdf</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/chem.201003683" target="_blank" >10.1002/chem.201003683</a>
Alternative languages
Result language
angličtina
Original language name
Anion-Free Bambus[6]uril and Its Supramolecular Properties
Original language description
Methods for the preparation of anion-free bambus[6]uril (BU6) are presented. They are based on the oxidation of iodide anion, which is bound inside the macrocycle, utilizing dark oxidation by hydrogen peroxide or photooxidation in the presence of titanium dioxide. Anion-free BU6 was found to be insoluble in any of the investigated solvents, however, it dissolves in the presence of the tetrabutylammonium salt of a suitable anion. The highest association constant (8.9x10E5 1/M) was found for the 1:1 complex of BU6 with TBAI in acetonitrile/water mixture. A number of crystal structures of BU6 complexes with various anions were obtained.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemistry - A European Journal
ISSN
0947-6539
e-ISSN
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Volume of the periodical
17
Issue of the periodical within the volume
20
Country of publishing house
DE - GERMANY
Number of pages
8
Pages from-to
5605-5612
UT code for WoS article
000290216000017
EID of the result in the Scopus database
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