The Power of Solvent in Altering the Course of Photorearrangements

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F11%3A00052645" target="_blank" >RIV/00216224:14310/11:00052645 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/ol102887f" target="_blank" >http://dx.doi.org/10.1021/ol102887f</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/ol102887f" target="_blank" >10.1021/ol102887f</a>

Result language
angličtina
Original language name
The Power of Solvent in Altering the Course of Photorearrangements
Original language description
A clean bifurcation between two important photochemical reactions through competition of a triplet state Type II H-abstraction reaction with a photo-Favorskii rearrangement for (o/p)-hydroxy-o-methylphenacyl esters that depends on the water content of the solvent has been established. The switch from the anhydrous Type II pathway that yields indanones to the aqueous-dependent pathway producing benzofuranones occurs abruptly at low water concentrations (~8%). The surprisingly clean yields suggest that such reactions are synthetically promising.
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
—

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)