Photoremovable Chiral Auxiliary

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F12%3A00058035" target="_blank" >RIV/00216224:14310/12:00058035 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1039/C1PP05096F" target="_blank" >http://dx.doi.org/10.1039/C1PP05096F</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/C1PP05096F" target="_blank" >10.1039/C1PP05096F</a>

Result language

angličtina

Original language name

Photoremovable Chiral Auxiliary

Original language description

A new concept of a photoremovable chiral auxiliary (PCA), based on the chiral benzoin chromophore, is introduced. This moiety can control the asymmetric formation of a Diels-Alder adduct, and then be removed in a subsequent photochemical step in high chemical and quantum yields. Selective formation of the products at up to 96% ee was observed in the presence of a Lewis acid catalyst in the case of a 2-methoxybenzoinyl chiral auxiliary.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CC - Organic chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach

Publication year

2012

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Photochemical & Photobiological Sciences

ISSN

1474-905X

e-ISSN

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Volume of the periodical

11

Issue of the periodical within the volume

3

Country of publishing house

GB - UNITED KINGDOM

Number of pages

8

Pages from-to

500-507

UT code for WoS article

000300991600008

EID of the result in the Scopus database

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