Syntheses and reactivity of alkyl 1-[N-(2-chloro-5-nitro-phenyl)-benzimidoyl] thioureas
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F12%3A00059253" target="_blank" >RIV/00216224:14310/12:00059253 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1080/17415993.2011.629094" target="_blank" >http://dx.doi.org/10.1080/17415993.2011.629094</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1080/17415993.2011.629094" target="_blank" >10.1080/17415993.2011.629094</a>
Alternative languages
Result language
angličtina
Original language name
Syntheses and reactivity of alkyl 1-[N-(2-chloro-5-nitro-phenyl)-benzimidoyl] thioureas
Original language description
A series of new alkyl 1-[N-(2-chloro-5-nitro-phenyl)-benzimidoyl] thioureas 3a?h were prepared from benzamides 1a?c. Benzimidoyl thioureas 3a?e afforded 5-nitro-2-phenyl-benzothiazole 5a?c under basic conditions via thiourea?isothiourea rearrangement andSNAr. A mechanistic rationalization supported by the direct formation of benzothioamide 8 and bis-benzimidoyl sulfide 9 derivatives from the reaction of imidoyl isothiocyanate 2 with bulky amines was supported.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal ofSulfur Chemistry
ISSN
1741-5993
e-ISSN
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Volume of the periodical
33
Issue of the periodical within the volume
1
Country of publishing house
US - UNITED STATES
Number of pages
15
Pages from-to
49-63
UT code for WoS article
000302057300007
EID of the result in the Scopus database
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