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A water soluble Al3+ selective colorimetric and fluorescent turn-on chemosensor and its application in living cell imaging

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F12%3A00079731" target="_blank" >RIV/00216224:14310/12:00079731 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1039/c2an35560d" target="_blank" >http://dx.doi.org/10.1039/c2an35560d</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/c2an35560d" target="_blank" >10.1039/c2an35560d</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    A water soluble Al3+ selective colorimetric and fluorescent turn-on chemosensor and its application in living cell imaging

  • Original language description

    An efficient water soluble fluorescent Al3+ receptor, 1-[[(2-furanylmethyl) imino]methyl]-2-naphthol (1-H) was synthesized and characterized by physico-chemical and spectroscopic tools along with single crystal X-ray crystallography. High selectivity andaffinity of 1-H towards Al3+ in HEPES buffer (DMSO/water: 1/100) of pH 7.4 at 25 degrees C showed it to be suitable for detection of intracellular Al3+ by fluorescence microscopy. Metal ions, viz. alkali (Na+, K+), alkaline earth (Mg2+, Ca2+), and transitionmetal ions (Ni2+, Zn2+, Cd2+, Co2+, Cu2+, Fe3+, Cr3+/6+, Hg2+) and Pb2+, Ag+ did not interfere. The lowest detection limit for Al3+ was calculated to be 6.03 x 10(-7) M in 100 mM HEPES buffer (DMSO/water: 1/100). Theoretical calculations have also been included in support of the configuration of the probe-aluminium complex.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2012

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Analyst

  • ISSN

    0003-2654

  • e-ISSN

  • Volume of the periodical

    137

  • Issue of the periodical within the volume

    17

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    7

  • Pages from-to

    3975-3981

  • UT code for WoS article

    000306932400014

  • EID of the result in the Scopus database