Laser desorption ionisation quadrupole ion trap time-of-flight mass spectrometry of titanium-carbon thin films
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F13%3A00068011" target="_blank" >RIV/00216224:14310/13:00068011 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/rcm.6564" target="_blank" >http://dx.doi.org/10.1002/rcm.6564</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/rcm.6564" target="_blank" >10.1002/rcm.6564</a>
Alternative languages
Result language
angličtina
Original language name
Laser desorption ionisation quadrupole ion trap time-of-flight mass spectrometry of titanium-carbon thin films
Original language description
RATIONALE: Titanium-carbon (Ti-C) ceramic thin films (abbreviated as n-TiC/a-C:H) are very important for industrial applications. However, their chemical structure is still not completely resolved. The aim of this study was to determine the chemical composition of such n-TiC/a-C:H layers prepared by balanced magnetron sputtering under various experimental conditions. METHODS: Mass spectrometric analysis of Ti-C thin films was carried out via laser desorption ionisation (LDI) using a quadrupole ion trapand reflectron time-of-flight analyser. The stoichiometry of clusters formed via laser ablation was determined, and the relative abundances of species for which the isotopic patterns overlaps were estimated using a least-squares program. RESULTS: Ti-C films were found to be composites of (i) pure and hydrogenated TiC, (ii) titanium oxycarbides, and (iii) titanium oxides of various degrees of hydrogenation (all embedded in an amorphous and/or diamond-like carbon matrix).
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Rapid Communications in Mass Spectrometry
ISSN
0951-4198
e-ISSN
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Volume of the periodical
27
Issue of the periodical within the volume
11
Country of publishing house
US - UNITED STATES
Number of pages
7
Pages from-to
1196-1202
UT code for WoS article
000318626500003
EID of the result in the Scopus database
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