Debromination of 2,4,6-tribromophenol coupled with biodegradation
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F13%3A00068020" target="_blank" >RIV/00216224:14310/13:00068020 - isvavai.cz</a>
Alternative codes found
RIV/00216275:25310/13:39896416 RIV/60461373:22330/13:43895210
Result on the web
<a href="http://dx.doi.org/10.2478/s11532-013-0231-6" target="_blank" >http://dx.doi.org/10.2478/s11532-013-0231-6</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.2478/s11532-013-0231-6" target="_blank" >10.2478/s11532-013-0231-6</a>
Alternative languages
Result language
angličtina
Original language name
Debromination of 2,4,6-tribromophenol coupled with biodegradation
Original language description
The application effect of aluminium and their alloys and mixtures with nickel was studied for the complete hydrodebromination of 2,4,6 tribromophenol to phenol in aqueous NaOH solution at room temperature. It was found that the Raney AlNi alloy can rapidly transform TBP to phenol. Removal efficiency of 25 mM TBP solution in aqueous NaOH solution at the end of 1h reaction was 100% using AlNi. The hydrodebromination is accompanied by the dissolution of aluminium and formation of soluble Al(OH)4 anions under these reaction conditions. After completion of the hydrodebromination reaction removal of the dissolved metals was achieved by precipitation of appropriate hydroxides by adjustment of the pH value and filtration, the filtrate was treated with Pseudomonas or Rhodococcus bacterial strains to degrade dissolved phenol. The combined application of both, chemical and biological treatments produced degradations of 100% of aromatic compounds.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/TA01010606" target="_blank" >TA01010606: Intermediates for non-ionic X-ray contrast media - application of principles of Green Chemistry</a><br>
Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Central European Journal of Chemistry
ISSN
1895-1066
e-ISSN
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Volume of the periodical
11
Issue of the periodical within the volume
6
Country of publishing house
CZ - CZECH REPUBLIC
Number of pages
9
Pages from-to
979-987
UT code for WoS article
000316762300011
EID of the result in the Scopus database
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