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Comparative Voltammetric Analysis of Adenine and Xanthine on a Pencil Graphite Electrode in the Presence of Copper Ions

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F13%3A00068033" target="_blank" >RIV/00216224:14310/13:00068033 - isvavai.cz</a>

  • Alternative codes found

    RIV/68081707:_____/13:00440605

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Comparative Voltammetric Analysis of Adenine and Xanthine on a Pencil Graphite Electrode in the Presence of Copper Ions

  • Original language description

    This work compares voltammetric responses of adenine (Ade) and xanthine (Xan) on a pencil graphite electrode (PeGE) in the presence of copper ions. For electroanalytical monitoring linear sweep voltammetry (LSV) in connection with elimination procedure (EVLS ? elimination voltammetry with linear scan), differential pulse voltammetry (DPV), and constant current potentiostatic stripping analysis (CPSA) were used. Both substances are oxidized on PeGE providing simple oxidation peaks in the absence of Cu(II) at about 0.8 V (Xan) and 1.1 V (Ade). Electrochemically produced Cu(I) ions give rise to new oxidation peaks corresponding to the oxidation of a sparingly soluble Cu(I)-purine complex at less positive potentials (~0.45 V) while the former oxidation purine peaks are increased. Compared to Ade the oxidative signal of Xan is split into two peaks depending on scan rate.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GAP205%2F10%2F2378" target="_blank" >GAP205/10/2378: Induced organization of biomolecules at interfaces by interacting with electrically charged surfaces as a tool for medical diagnostics</a><br>

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2013

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Int. J. Electrochem. Sci.

  • ISSN

    1452-3981

  • e-ISSN

  • Volume of the periodical

    8

  • Issue of the periodical within the volume

    4

  • Country of publishing house

    RS - THE REPUBLIC OF SERBIA

  • Number of pages

    12

  • Pages from-to

    4397-4408

  • UT code for WoS article

    000318217200004

  • EID of the result in the Scopus database