New Supported Catalytic Binary System for the Green and Sustainable Production of Cyanogen Fumigant Optimization Using Artificial Neural Network

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F14%3A00073302" target="_blank" >RIV/00216224:14310/14:00073302 - isvavai.cz</a>

Result on the web

<a href="http://www.ethanpublishing.com/index.php?m=content&c=index&a=show&catid=170&id=271" target="_blank" >http://www.ethanpublishing.com/index.php?m=content&c=index&a=show&catid=170&id=271</a>

DOI - Digital Object Identifier

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Result language

angličtina

Original language name

New Supported Catalytic Binary System for the Green and Sustainable Production of Cyanogen Fumigant Optimization Using Artificial Neural Network

Original language description

We report a new binary Cu(n)/Fe(m) supported catalytic system for a green and sustainable oxidation of hydrogen cyanide to cyanogen by hydrogen peroxide action. The binary catalytic system Cu(n)/Fe(m), wherein n has the value of I or II, m is II or III,is supported on an acidic cation-exchanger resin. Oxidation process was carried out in a mixture of methanol-water as a solvent. We found that only two undesirable by-products, carbon dioxide and elementary nitrogen are formed during an oxidation of hydrogen cyanide. Furthermore, we observed that the relative content of the target cyanogen and undesirably CO2 depends on all input parameters, i.e. on a character and amount of an applied resin, quantity of both metal ions Fe and Cu supported on catalyst,presence and character of a potential ligand (acetyl acetone or 2,2´-bipyridyl for the stabilization of possible metal oxidation states), input rates of both reagents, and reaction temperature, respectively.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CC - Organic chemistry

OECD FORD branch

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Project

<a href="/en/project/TA03010633" target="_blank" >TA03010633: Advanced sustainable technologies for fine chemical syntheses based on cyanic chemistry</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2014

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Chemical Engineering and Chemistry Research (Chemistry )

ISSN

2333-9195

e-ISSN

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Volume of the periodical

1

Issue of the periodical within the volume

5

Country of publishing house

US - UNITED STATES

Number of pages

12

Pages from-to

302-313

UT code for WoS article

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EID of the result in the Scopus database

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