Water-mediated inclusion of benzoates and tosylates inside the bambusuril macrocycle

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F14%3A00073514" target="_blank" >RIV/00216224:14310/14:00073514 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1039/c3cc47828a" target="_blank" >http://dx.doi.org/10.1039/c3cc47828a</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c3cc47828a" target="_blank" >10.1039/c3cc47828a</a>

Result language
angličtina
Original language name
Water-mediated inclusion of benzoates and tosylates inside the bambusuril macrocycle
Original language description
A supramolecular complex between benzoates and a bambusuril crystallizes out immediately after mixing in chloroform but only in the presence of residual water molecules. In this complex each of the two portals of the macrocycle is occupied by one benzoate. Carboxylate groups are connected through hydrogen bonding interactions with one molecule of water positioned between them in the center of the bambusuril cavity. Similar water assisted host?guest behavior was also observed when tosylates instead of benzoates were used.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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