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Generation of novel AumSen clusters via laser ablation synthesis. Laser desorption ionisation time-of-flight mass spectrometry

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F14%3A00073737" target="_blank" >RIV/00216224:14310/14:00073737 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Generation of novel AumSen clusters via laser ablation synthesis. Laser desorption ionisation time-of-flight mass spectrometry

  • Original language description

    Several gold selenium complexes are known (e.g., [Au 2 (Se 2 )(Se 3 )] 2- , [Au 2 (Se 2 )(Se 4 )] 2- and [Au 2 Se 2 (Se 4 ) 2 ] 2- ). Minerals such as fischesserite (Ag 3 AuSe 2 ), kurilite ((Au,Ag) 2 (Te,Se,S) 2 ) and petrovskite ((AuAg)(S,Se)) are found in nature. Laser desorption ionisation time-of-flight mass spectrometry (LDI TOF MS) is powerful technique to generate and study clusters formed during laser ablation of various materials leading to metal chalcogenides [1] or gold carbides [2], for example. The aim of this work is to study the generation of Au m Se n clusters via laser ablation synthesis (LAS) using mixtures of GNPs (or auric acid) with selenium in various molar ratios as precursors. We have found that GNPs are chemisorbed on seleniumsurface leading to the formation of a kind of nano-composite as confirmed by scanning electron microscope (SEM) analysis.

  • Czech name

  • Czech description

Classification

  • Type

    O - Miscellaneous

  • CEP classification

    CB - Analytical chemistry, separation

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů