Peroxido Complexes of Vanadium(V) as Ligands. Crystal Structures of [Cd(NH3)(6)] [{VO(O-2)(2)(OH)}(2){mu-Cd(NH3)(4)}] and [{VO(O-2)(2)(Im)}(2){mu-Cu(Im)(4)}] (Im = Imidazole)

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F14%3A00080230" target="_blank" >RIV/00216224:14310/14:00080230 - isvavai.cz</a>

Alternative codes found

RIV/61388955:_____/14:00431468

Result on the web

<a href="http://dx.doi.org/10.1021/ic500066p" target="_blank" >http://dx.doi.org/10.1021/ic500066p</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/ic500066p" target="_blank" >10.1021/ic500066p</a>

Result language

angličtina

Original language name

Peroxido Complexes of Vanadium(V) as Ligands. Crystal Structures of [Cd(NH3)(6)] [{VO(O-2)(2)(OH)}(2){mu-Cd(NH3)(4)}] and [{VO(O-2)(2)(Im)}(2){mu-Cu(Im)(4)}] (Im = Imidazole)

Original language description

Two novel heterometallic complexes [Cd(NH3)(6)][{VO-(O-2)(2)(OH)}(2){mu-Cd(NH3)(4)}] (2) and [{VO(O-2)(2)(Im)}(2){mu-Cu(Im)(4)}] (3) (Im = imidazole) containing peroxidovanadium complexes as metalloligands were prepared and characterized by spectral methods. X-ray single-crystal analysis revealed the presence of unique trinuclear complexes in the crystal structures of 2 and 3. The structure of 2 contains an anionic complex, whose two {VO(O-2)(2)(OH)}(2-) ions are interconnected by a {mu-Cd(NH3)(4)}(2+)group. Compound 3 is a trinuclear neutral complex comprising two {VO(O-2)(2)(Im)}(-) ions and a single bridging {mu-Cu(Im)(4)}(2+) group. The bonding via an equatorial OH- ligand in 2 and via a doubly bonded apical oxygen atom in 3 represents coordination modes previously unobserved for diperoxidovanadium complexes.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2014

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Inorganic Chemistry

ISSN

0020-1669

e-ISSN

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Volume of the periodical

53

Issue of the periodical within the volume

10

Country of publishing house

US - UNITED STATES

Number of pages

7

Pages from-to

5037-5043

UT code for WoS article

000336240400030

EID of the result in the Scopus database

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