Anion Binding Inside a Bambus[6]uril Macrocycle in Chloroform
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F15%3A00081318" target="_blank" >RIV/00216224:14310/15:00081318 - isvavai.cz</a>
Result on the web
<a href="http://onlinelibrary.wiley.com/doi/10.1002/cplu.201500345/abstract;jsessionid=652F5507CDB81CAB25996438A0DC0635.f01t02?systemMessage=Wiley+Online+Library+will+be+unavailable+for+up+to+3+hours+on+Saturday+19th+March+2016+from++11%3A00-14%3A00+GMT+%2F+07%3A" target="_blank" >http://onlinelibrary.wiley.com/doi/10.1002/cplu.201500345/abstract;jsessionid=652F5507CDB81CAB25996438A0DC0635.f01t02?systemMessage=Wiley+Online+Library+will+be+unavailable+for+up+to+3+hours+on+Saturday+19th+March+2016+from++11%3A00-14%3A00+GMT+%2F+07%3A</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/cplu.201500345" target="_blank" >10.1002/cplu.201500345</a>
Alternative languages
Result language
angličtina
Original language name
Anion Binding Inside a Bambus[6]uril Macrocycle in Chloroform
Original language description
Bambus[6]urils are a class of neutral anion receptors with outstanding binding properties in various solvents. The host-guest associations of bambusurils in aqueous environments have been investigated in detail, but their behavior in nonpolar solvents has not yet been reported. This paper presents isothermal calorimetry and (HNMR)-H-1 data on the binding of dodecabenzylbambus[6]uril (Bn12BU[6]) to seventeen anions in chloroform. Under these conditions, anion inclusion in the macrocycle appears to be enthalpy-driven, yielding complexes with stability constants of up to 10(10)m(-1). Perchlorate was optimally sized for inclusion in Bn12BU[6], while larger anions exhibited significantly lower affinity for the macrocycle. In addition, complexes of bambusuril and anions can be differentiated by NMR analysis based on the unique chemical shifts of characteristic peaks in their spectra. This finding was used to perform quantitative and qualitative analysis of multiple anion mixtures.
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
—
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
CHEMPLUSCHEM
ISSN
2192-6506
e-ISSN
—
Volume of the periodical
80
Issue of the periodical within the volume
11
Country of publishing house
DE - GERMANY
Number of pages
6
Pages from-to
1601-1606
UT code for WoS article
000364528600003
EID of the result in the Scopus database
—