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Anion Binding Inside a Bambus[6]uril Macrocycle in Chloroform

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F15%3A00081318" target="_blank" >RIV/00216224:14310/15:00081318 - isvavai.cz</a>

  • Result on the web

    <a href="http://onlinelibrary.wiley.com/doi/10.1002/cplu.201500345/abstract;jsessionid=652F5507CDB81CAB25996438A0DC0635.f01t02?systemMessage=Wiley+Online+Library+will+be+unavailable+for+up+to+3+hours+on+Saturday+19th+March+2016+from++11%3A00-14%3A00+GMT+%2F+07%3A" target="_blank" >http://onlinelibrary.wiley.com/doi/10.1002/cplu.201500345/abstract;jsessionid=652F5507CDB81CAB25996438A0DC0635.f01t02?systemMessage=Wiley+Online+Library+will+be+unavailable+for+up+to+3+hours+on+Saturday+19th+March+2016+from++11%3A00-14%3A00+GMT+%2F+07%3A</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/cplu.201500345" target="_blank" >10.1002/cplu.201500345</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Anion Binding Inside a Bambus[6]uril Macrocycle in Chloroform

  • Original language description

    Bambus[6]urils are a class of neutral anion receptors with outstanding binding properties in various solvents. The host-guest associations of bambusurils in aqueous environments have been investigated in detail, but their behavior in nonpolar solvents has not yet been reported. This paper presents isothermal calorimetry and (HNMR)-H-1 data on the binding of dodecabenzylbambus[6]uril (Bn12BU[6]) to seventeen anions in chloroform. Under these conditions, anion inclusion in the macrocycle appears to be enthalpy-driven, yielding complexes with stability constants of up to 10(10)m(-1). Perchlorate was optimally sized for inclusion in Bn12BU[6], while larger anions exhibited significantly lower affinity for the macrocycle. In addition, complexes of bambusuril and anions can be differentiated by NMR analysis based on the unique chemical shifts of characteristic peaks in their spectra. This finding was used to perform quantitative and qualitative analysis of multiple anion mixtures.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CC - Organic chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2015

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    CHEMPLUSCHEM

  • ISSN

    2192-6506

  • e-ISSN

  • Volume of the periodical

    80

  • Issue of the periodical within the volume

    11

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    6

  • Pages from-to

    1601-1606

  • UT code for WoS article

    000364528600003

  • EID of the result in the Scopus database