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Innovative preconcentration technique on polymer sorbent for simultanoues determination of platinum group metals in the waters and lichen Hypogymnia physodes

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F16%3A00112359" target="_blank" >RIV/00216224:14310/16:00112359 - isvavai.cz</a>

  • Result on the web

    <a href="https://www.prt-parlar.de/download_feb_2016/" target="_blank" >https://www.prt-parlar.de/download_feb_2016/</a>

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Innovative preconcentration technique on polymer sorbent for simultanoues determination of platinum group metals in the waters and lichen Hypogymnia physodes

  • Original language description

    This study is focused on optimization of preconcentration procedure of trace amounts of platinum group metals (PGMs) by solid phase extraction. Amberlite polystyrene-divinylbezene based sorbent was used for this purpose. Under the optimizing process were optimize number of parameters such as pH value of sorption; type and concentration of complexing agent; concentration and type of cationic surfactant; type, pH, and volume of eluent mixture; acidity of final solution and various interfering influences (presence of various ions, matrix effects). Ammonium-pyrrolidindithiocarbamate, thiourea, 4-(2-pyridylazo) resorcinol and 8-hydroxyquinoline-5-sulfonic acid were used as complexing agents for PGMs. Sorbent was conditioned using cationic surfactant solution. Benzyldimethyltetradecyl ammonium chloride, N-(alpha-carbethoxypentadecyl)trimethyl ammonium bromide and benzyldimethyldodecyl ammonium bromide were tested. Mixture of acetonitrile and HCl was proved as eluent. The influences of various concentrations of hydrochloric acid during the complexation, elution and partial evaporation of the eluent prior the determination were tested. Effects of various elements and ions were studied during the sorption and retention on the above mentioned sorbent. Simultaneous determination of PGMs was performed by ICP-MS spectrometer using helium collision cell and internal standard. Detection limits for individual elements at discussed conditions were evaluated. The optimized method of solid phase extraction was applied to spiked real water samples and lichens for testing influences of matrix and efficient of sorption process. It was discovered that recovery ratio of sorption process is diverse for individual studied elements. Acceptable results was achieved for Platinum and Palladium which showed recovery ratio about 100 % and 95 % for Osmium.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10511 - Environmental sciences (social aspects to be 5.7)

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2016

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Fresenius Environmental Bulletin

  • ISSN

    1018-4619

  • e-ISSN

    1610-2304

  • Volume of the periodical

    25

  • Issue of the periodical within the volume

    12

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    8

  • Pages from-to

    5172-5179

  • UT code for WoS article

    000391345600011

  • EID of the result in the Scopus database

    2-s2.0-85034053501