Origin of scapolite-hosted sapphire (corundum) near Kimmirut, Baffin Island, Nunavut, Canada

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F17%3A00095032" target="_blank" >RIV/00216224:14310/17:00095032 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.3749/canmin.1700018" target="_blank" >http://dx.doi.org/10.3749/canmin.1700018</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3749/canmin.1700018" target="_blank" >10.3749/canmin.1700018</a>

Result language

angličtina

Original language name

Origin of scapolite-hosted sapphire (corundum) near Kimmirut, Baffin Island, Nunavut, Canada

Original language description

Gem-quality corundum (sapphire) occurs in scapolite-rich calc-silicate rock hosted in marble of the Lake Harbour Group near Kimmirut, southern Baffin Island. A deposit of blue and colorless gem corundum (Beluga occurrence) is compared to a similar calc-silicate pod generally lacking corundum but containing nepheline (Bowhead occurrence) and located 170 m to the SSW. Corundum formation was made possible by three equally important sequential metamorphic reactions: (1) formation of nepheline, diopside, and K-feldspar (inferred) at granulite facies peak metamorphic conditions; (2) partial retrograde replacement of the peak assemblage by phlogopite, oligoclase, calcite, and scapolite (Me-50-Me-67) as a result of CO2-, H2O-, Cl-, F-bearing fluid influx at 1782.5 +/- 3.7 Ma (P-T 720 degrees C, 6.2 kbar); and (3) retrograde breakdown of scapolite + nepheline (with CO2-and H2O-bearing fluid) to form albite, muscovite, corundum, and calcite. Late, low-temperature zeolite mineralization is common in corundum-bearing zones. Based on thermodynamic models, the corundum-forming reaction only occurs in a 100 degrees C window with an upper limit determined by scapolite-nepheline stability, and a lower limit determined by the formation of Al-silicate rather than corundum. The protolith is inferred to be dolomitic argillaceous marl with no evidence to suggest the initial presence of evaporites. The enrichment of trace metals V and Cr, and the depletion of Co, Ni, and Mn, suggest reducing diagenetic conditions in the initial sediment. Beluga calc-silicate rock is strongly depleted in REE. Oxy-dravite delta B-11 (+3.9 +/- 0.7%) is consistent with a marine boron source. The oxygen isotope composition of corundum (delta O-18(VSMOW) = 16.4 +/- 0.1%) is comparable to that of corundum in marble or desilicated pegmatite associated with marble.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

10500 - Earth and related environmental sciences

Project

<a href="/en/project/GA17-17276S" target="_blank" >GA17-17276S: Tourmaline – an indicator of geological processes</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2017

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Canadian Mineralogist

ISSN

0008-4476

e-ISSN

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Volume of the periodical

55

Issue of the periodical within the volume

4

Country of publishing house

CA - CANADA

Number of pages

31

Pages from-to

669-699

UT code for WoS article

000406369600008

EID of the result in the Scopus database

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