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Pulse Biamperometry for Electrochemical Detection in Flow Systems

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F17%3A00113623" target="_blank" >RIV/00216224:14310/17:00113623 - isvavai.cz</a>

  • Result on the web

    <a href="https://www.bestservis.eu/upload/file/Sbornik_metody17.pdf" target="_blank" >https://www.bestservis.eu/upload/file/Sbornik_metody17.pdf</a>

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    čeština

  • Original language name

    Pulse Biamperometry for Electrochemical Detection in Flow Systems

  • Original language description

    A novel, pulse biamperometric technique was developed for enhancing the intensity of currents measured during electrochemical detection in flow systems. Two polarizable elctrodes in form of microfibers made of carbon platinum or their combination were utilized for biamperometric detection of dopamine in capillary detectors. Using a sequence of positive and negative potentials, measured signals were two orders of magnitude higher than those obtained for direct biamperometry. Such amplification resulted in forty times increase in sensitivity for dopamine detection. In a pulse mode, the passivation of electrodes was significantly reduced and the repeatability of individiual injections was markedly imporved.

  • Czech name

    Pulse Biamperometry for Electrochemical Detection in Flow Systems

  • Czech description

    A novel, pulse biamperometric technique was developed for enhancing the intensity of currents measured during electrochemical detection in flow systems. Two polarizable elctrodes in form of microfibers made of carbon platinum or their combination were utilized for biamperometric detection of dopamine in capillary detectors. Using a sequence of positive and negative potentials, measured signals were two orders of magnitude higher than those obtained for direct biamperometry. Such amplification resulted in forty times increase in sensitivity for dopamine detection. In a pulse mode, the passivation of electrodes was significantly reduced and the repeatability of individiual injections was markedly imporved.

Classification

  • Type

    D - Article in proceedings

  • CEP classification

  • OECD FORD branch

    10406 - Analytical chemistry

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2017

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    XXXVII MODERNI ELEKTROCHEMICKE METODY

  • ISBN

    9788090522152

  • ISSN

  • e-ISSN

  • Number of pages

    4

  • Pages from-to

    104-107

  • Publisher name

    LENKA SRSENOVA-BEST SERVIS

  • Place of publication

    USTI NAD LABEM

  • Event location

    Jetrichovice, CZECH REPUBLIC

  • Event date

    May 15, 2017

  • Type of event by nationality

    EUR - Evropská akce

  • UT code for WoS article

    000432424300023