Bambusuril analogs based on alternating glycoluril and xylylene units
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F19%3A00107546" target="_blank" >RIV/00216224:14310/19:00107546 - isvavai.cz</a>
Result on the web
<a href="https://www.beilstein-journals.org/bjoc/articles/15/124" target="_blank" >https://www.beilstein-journals.org/bjoc/articles/15/124</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.3762/bjoc.15.124" target="_blank" >10.3762/bjoc.15.124</a>
Alternative languages
Result language
angličtina
Original language name
Bambusuril analogs based on alternating glycoluril and xylylene units
Original language description
The glycoluril monomer is a popular building block in supramolecular chemistry as it is used for the synthesis of versatile host molecules which can interact with cationic, anionic or neutral guest molecules. Here we present the design and synthesis of a new hybrid macrocycle containing glycoluril and aromatic units. The reaction afforded a mixture of macrocyclic homologues from which a two-membered macrocycle was isolated as the main product. Two disastereomers of the macrocycle were separated and characterized by means of NMR spectroscopy and X-ray crystallography. Conformational changes of these diastereomers were investigated using DFT models and variable-temperature NMR.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Beilstein journal of organic chemistry
ISSN
1860-5397
e-ISSN
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Volume of the periodical
15
Issue of the periodical within the volume
June
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
1268-1274
UT code for WoS article
000471672700001
EID of the result in the Scopus database
2-s2.0-85068332372