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Bambusuril Macrocycles as Mediators of Supramolecular Interactions: Application to the Europium Cage Helicate

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F21%3A00119181" target="_blank" >RIV/00216224:14310/21:00119181 - isvavai.cz</a>

  • Result on the web

    <a href="https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202005140" target="_blank" >https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202005140</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/chem.202005140" target="_blank" >10.1002/chem.202005140</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Bambusuril Macrocycles as Mediators of Supramolecular Interactions: Application to the Europium Cage Helicate

  • Original language description

    Herein, it is shown how bambusurils can be used for tuning and/or characterizing supramolecular systems. Indeed, the addition of bambusurils as anion scavengers to metal-mediated self-assemblies allows manipulation of the subtle equilibria in the given system. This is demonstrated for the case of the tetranuclear europium helical cage, which is well suited to different applications. Among the reported results, experimental evidence is provided showing that perchlorate and triflate anions act as a molecular template for the cage assembly. The complexation of inorganic anions with neutral bambusurils resulted in bulky non-coordinating counterions that may trigger the self-assembly process or stimulate specific interactions between components. Moreover, bambusuril was able to selectively remove coordinating nitrates from the mixture with non-coordinating anions, enabling the regeneration of the helical cage.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10400 - Chemical sciences

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2021

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Chemistry - A European Journal

  • ISSN

    0947-6539

  • e-ISSN

  • Volume of the periodical

    27

  • Issue of the periodical within the volume

    17

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    6

  • Pages from-to

    5492-5497

  • UT code for WoS article

    000621806300001

  • EID of the result in the Scopus database

    2-s2.0-85101617880