Bambusuril Macrocycles as Mediators of Supramolecular Interactions: Application to the Europium Cage Helicate
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F21%3A00119181" target="_blank" >RIV/00216224:14310/21:00119181 - isvavai.cz</a>
Result on the web
<a href="https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202005140" target="_blank" >https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202005140</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/chem.202005140" target="_blank" >10.1002/chem.202005140</a>
Alternative languages
Result language
angličtina
Original language name
Bambusuril Macrocycles as Mediators of Supramolecular Interactions: Application to the Europium Cage Helicate
Original language description
Herein, it is shown how bambusurils can be used for tuning and/or characterizing supramolecular systems. Indeed, the addition of bambusurils as anion scavengers to metal-mediated self-assemblies allows manipulation of the subtle equilibria in the given system. This is demonstrated for the case of the tetranuclear europium helical cage, which is well suited to different applications. Among the reported results, experimental evidence is provided showing that perchlorate and triflate anions act as a molecular template for the cage assembly. The complexation of inorganic anions with neutral bambusurils resulted in bulky non-coordinating counterions that may trigger the self-assembly process or stimulate specific interactions between components. Moreover, bambusuril was able to selectively remove coordinating nitrates from the mixture with non-coordinating anions, enabling the regeneration of the helical cage.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10400 - Chemical sciences
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemistry - A European Journal
ISSN
0947-6539
e-ISSN
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Volume of the periodical
27
Issue of the periodical within the volume
17
Country of publishing house
DE - GERMANY
Number of pages
6
Pages from-to
5492-5497
UT code for WoS article
000621806300001
EID of the result in the Scopus database
2-s2.0-85101617880