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Nitro- and oxy-PAHs in grassland soils from decade-long sampling in central Europe

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F22%3A00126743" target="_blank" >RIV/00216224:14310/22:00126743 - isvavai.cz</a>

  • Result on the web

    <a href="https://link.springer.com/article/10.1007/s10653-021-01066-y" target="_blank" >https://link.springer.com/article/10.1007/s10653-021-01066-y</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s10653-021-01066-y" target="_blank" >10.1007/s10653-021-01066-y</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Nitro- and oxy-PAHs in grassland soils from decade-long sampling in central Europe

  • Original language description

    Long-term exposure to polycyclic aromatic hydrocarbons (PAHs) and their nitrated (NPAHs) and oxygenated (OPAHs) derivatives can cause adverse health effects due to their carcinogenicity, mutagenicity and oxidative potential. The distribution of PAH derivatives in the terrestrial environment has hardly been studied, although several PAH derivatives are ubiquitous in air and long-lived in soil and water. We report the multi-annual variations in the concentrations of NPAHs, OPAHs and PAHs in soils sampled at a semi-urban (Mokra, Czech Republic) and a regional background site (Kosetice, Czech Republic) in central Europe. The concentrations of the sigma(18)NPAHs and the sigma(11+2)OPAHs and O-heterocycles were 0.31 +/- 0.23 ng g(-1) and 4.03 +/- 3.03 ng g(-1), respectively, in Kosetice, while slightly higher concentrations of 0.54 +/- 0.45 ng g(-1) and 5.91 +/- 0.45 ng g(-1), respectively, were found in soil from Mokra. Among the 5 NPAHs found in the soils, 1-nitropyrene and less so 6-nitrobenzo(a)pyrene were most abundant. The OPAHs were more evenly distributed. The ratios of the PAH derivatives to their parent PAHs in Kosetice indicate that they were long-range transported to the background site. Our results show that several NPAHs and OPAHs are abundant in soil and that gas-particle partitioning is a major factor influencing the concentration of several semi-volatile NPAHs and OPAHs in the soils. Complete understanding of the long-term variations of NPAH and OPAH concentrations in soil is limited by the lack of kinetic data describing their formation and degradation.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10511 - Environmental sciences (social aspects to be 5.7)

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2022

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    ENVIRONMENTAL GEOCHEMISTRY AND HEALTH

  • ISSN

    0269-4042

  • e-ISSN

  • Volume of the periodical

    44

  • Issue of the periodical within the volume

    8

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    23

  • Pages from-to

    2743-2765

  • UT code for WoS article

    000686865300001

  • EID of the result in the Scopus database

    2-s2.0-85113185377