Effect of sulfur precursors on hydrothermal growth of MoS2 nanostructures and its visible-light-driven photocatalytic activities

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F23%3A00131170" target="_blank" >RIV/00216224:14310/23:00131170 - isvavai.cz</a>

Result on the web

<a href="https://www.sciencedirect.com/science/article/pii/S0022286023000303?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0022286023000303?via%3Dihub</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.molstruc.2023.134929" target="_blank" >10.1016/j.molstruc.2023.134929</a>

Result language

angličtina

Original language name

Effect of sulfur precursors on hydrothermal growth of MoS2 nanostructures and its visible-light-driven photocatalytic activities

Original language description

The molybdenum disulfide (MoS2) nanostructures such as nanosheets, nanoflowers, nanoparticles, and nanoflakes are promising candidate materials for environmental pollution control. In this work, the effect of sulfur precursors i.e. thioacetamide, thiourea, and elemental sulfur on the morphology of hydrother-mally grown MoS2 material was studied followed by their visible-light-driven photocatalytic activities toward methyl orange (MO) dye degradation at ambient conditions. Interestingly under scanning electron microscope (SEM) images, the morphologies of synthesized materials were seen to consist of systematic nanosheets, aggregates, and agglomerates. Raman spectroscopy and XRD studies suggested that the grown materials were composed of primarily 1T-2H mixed phase of MoS2 along with a minor oxide phase of molybdenum. Moreover, photocatalytic MO dye degradation activities exhibited by thioacetamide-grown MoS2 nanostructures were found to be better than those of elemental sulfur and thiourea counterparts. The kinetic rates of degradation towards MO dye by materials synthesized with thioacetamide, elemental sulfur, and thiourea were found to be 0.0 0804 min -1, 0.0 0614 min -1, and 0.0 0531 min -1, respectively. The relatively better photocatalytic activities exhibited by thioacetamide-grown MoS2 material were at-tributed to its predominant nanosheet morphology and the presence of a greater amount of MoS2 con-tents. This work will be helpful for a better understanding of morphological control hydrothermal syn-thesis of MoS2-based materials and their subsequent organic dye degradation activities.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

10403 - Physical chemistry

Project

—

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2023

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Molecular Structure

ISSN

0022-2860

e-ISSN

—

Volume of the periodical

1278

Issue of the periodical within the volume

April 2023

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

8

Pages from-to

1-8

UT code for WoS article

000924524100001

EID of the result in the Scopus database

2-s2.0-85146542497