Mono cationic palladium(II): Synthesis, characterization and catalytic activity in Suzuki coupling

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14740%2F11%3A00053533" target="_blank" >RIV/00216224:14740/11:00053533 - isvavai.cz</a>
Result on the web
<a href="http://www.sciencedirect.com/science/article/pii/S0020169311003161" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0020169311003161</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ica.2011.03.045" target="_blank" >10.1016/j.ica.2011.03.045</a>

Result language
angličtina
Original language name
Mono cationic palladium(II): Synthesis, characterization and catalytic activity in Suzuki coupling
Original language description
Monocationic five and four-coordinate Pd(II) complexes have been synthesized in a facile manner involving the reaction of (COD) PdCl(2) with AgPF(6) and a nitrogen or phosphorus ligand. Complexes synthesized via this route are five coordinate [PdCl(2,9-Me(2)Phen)(2)]PF(6) 2 and four coordinate [L(3)PdCl]PF(6) (L = PPh(3), 3; P(p-Tol)(3), 4; P(OEt)(3); 5). ESI-MS studies at varying cone-voltage indicated ligand dissociation depending upon ligand cone-angle. A halo-bridged complex [PdCl(mu-Cl){P(p-Tol)(3)}](2) 7 has been isolated from 4 in methanol. The cationic complexes have been screened as catalyst in Suzuki coupling involving aryl halide and phenylboronic acid. Complex 4 showed appreciable turnover.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach

Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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