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Structure and NMR chemical shifts in Pt(IV) and Ir(III) complexes: Validation of DFT methods

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14740%2F12%3A00057284" target="_blank" >RIV/00216224:14740/12:00057284 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Structure and NMR chemical shifts in Pt(IV) and Ir(III) complexes: Validation of DFT methods

  • Original language description

    Evaluation of DFT methods to calculate structure and NMR chemical shifts for heavy-transition-metal complexes with modified adenines was discussed. Particularly we focused on the role of density functionals and basis sets in geometry optimizations and important role of exact-exchange admixture in functional for the calculation of the NMR chemical shifts for Pt(IV) and Ir(III) complexes.

  • Czech name

  • Czech description

Classification

  • Type

    O - Miscellaneous

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GAP206%2F12%2F0539" target="_blank" >GAP206/12/0539: Structure and dynamics of transition-metal complexes and their interaction with cavitands</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2012

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů