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Construction of Larger Molecular Aluminophosphate Cages from the Cyclic Four-Ring Building Unit

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14740%2F14%3A00075992" target="_blank" >RIV/00216224:14740/14:00075992 - isvavai.cz</a>

  • Result on the web

    <a href="http://www.ncbi.nlm.nih.gov/pubmed/24617956" target="_blank" >http://www.ncbi.nlm.nih.gov/pubmed/24617956</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1021/ic500083a" target="_blank" >10.1021/ic500083a</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Construction of Larger Molecular Aluminophosphate Cages from the Cyclic Four-Ring Building Unit

  • Original language description

    New molecular aluminophosphates of different nuclearity are synthesized by a stepwise process and structurally characterized. The alkane elimination reaction of bis(trimethysiloxy)phosphoric acid, OP(OH)(OSiMe3)2, with trialkylalanes, AlR3 (R = Me, Et, iBu), provides the cyclic dimeric aluminophosphates, [(AlR2{m2-O2P(OSiMe3)2})2] (R = Me (1), Et (2), iBu (3)). Unsymmetrically substituted cyclic aluminophosphonate [(AlMe2{m2-O2P(OSiMe3)(cHex)})2] (cis/trans 4), is prepared by dealkylsilylation reactionof cHexP(O)(OSiMe3)2 with AlMe3. The molecules 1-4 containing the [Al2(m2-O2P)2] inorganic core are structural and spectroscopic models for the single four-ring (S4R) secondary building units (SBU) of zeolite frameworks. Compound 1 serves as a starting point in construction of larger molecular units by reactions with OP(OH)(OSiMe3)2 as a cage-extending reagent, and with diketones, such as Hhfacac (1,1,1,5,5,5-hexafluoropentan-2,4-dione) and Hacac (pentan-2,4-dione), as capping reagents.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Inorganic Chemistry

  • ISSN

    0020-1669

  • e-ISSN

  • Volume of the periodical

    53

  • Issue of the periodical within the volume

    7

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    10

  • Pages from-to

    3753-3762

  • UT code for WoS article

    000334092500062

  • EID of the result in the Scopus database