Interaction of ferroceneboronic acid with diols at aqueous and non-aqueous conditions - signalling and binding abilities of an electrochemical probe for saccharides

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14740%2F15%3A00082937" target="_blank" >RIV/00216224:14740/15:00082937 - isvavai.cz</a>
Result on the web
<a href="http://www.sciencedirect.com/science/article/pii/S001346861402444X" target="_blank" >http://www.sciencedirect.com/science/article/pii/S001346861402444X</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.electacta.2014.12.009" target="_blank" >10.1016/j.electacta.2014.12.009</a>

Result language
angličtina
Original language name
Interaction of ferroceneboronic acid with diols at aqueous and non-aqueous conditions - signalling and binding abilities of an electrochemical probe for saccharides
Original language description
Ferroceneboronic acid (FcBA) was employed as a model compound for clarification of binding and signalling properties of molecular probe for saccharides. As the simplest electrochemically active boronic acid, its interactions with diverse diols were studied in homogeneous phase under aqueous and non-aqueous conditions. The FcBA-diol system was examined by cyclic voltammetry resulting in two redox pairs corresponding to free and bound forms of FcBA. Redox potential of the bound form of FcBA was shifted inthe cathodic direction in aqueous conditions due to coordination of the hydroxyl group to the boron atom. Oppositely, the anodic shift of the redox potential was observed upon the interaction of FcBA with diols in non-aqueous solvents. The binding properties and signalling mechanism of electrochemically active boronic acids were deduced and the assumptions resulting from the electrochemical behaviour were confirmed by 1H and 11B NMR spectroscopies.
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
—

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)