Ferrocene-Boronic Acid?Fructose Binding Based on Dual- Plate Generator?Collector Voltammetry and Square-Wave Voltammetry

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14740%2F15%3A00086932" target="_blank" >RIV/00216224:14740/15:00086932 - isvavai.cz</a>
Result on the web
<a href="http://onlinelibrary.wiley.com/doi/10.1002/celc.201500016/full" target="_blank" >http://onlinelibrary.wiley.com/doi/10.1002/celc.201500016/full</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/celc.201500016" target="_blank" >10.1002/celc.201500016</a>

Result language
angličtina
Original language name
Ferrocene-Boronic Acid?Fructose Binding Based on Dual- Plate Generator?Collector Voltammetry and Square-Wave Voltammetry
Original language description
The interaction of ferrocene-boronic acid with fructose is investigated in aqueous 0.1 M phosphate buffer at pH 7, 8 and 9. Two voltammetric methods, based on 1) a dual-plate generator?collector micro-trench electrode (steady state) and 2) a square-wavevoltammetry (transient) method, are applied and compared in terms of mechanistic resolution. A combination of experimental data is employed to obtain new insights into the binding rates and the cumulative binding constants for both the reduced ferrocene-boronic acid (pH dependent and weakly binding) and for the oxidised ferrocene-boronic acid (pH independent and strongly binding).
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
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Project
<a href="/en/project/ED1.1.00%2F02.0068" target="_blank" >ED1.1.00/02.0068: Central european institute of technology</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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