Solvent Effects on Ion-Receptor Interactions in the Presence of an External Electric Field
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14740%2F16%3A00091281" target="_blank" >RIV/00216224:14740/16:00091281 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1039/C6CP05781K" target="_blank" >http://dx.doi.org/10.1039/C6CP05781K</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/C6CP05781K" target="_blank" >10.1039/C6CP05781K</a>
Alternative languages
Result language
angličtina
Original language name
Solvent Effects on Ion-Receptor Interactions in the Presence of an External Electric Field
Original language description
In this work we investigated the influence of an external electric field on the arrangement of solvent shell around ions interacting with a carbon-based receptor. Our survey reveals that the mechanism of interaction between a monoatomic ion and a pi-type ion receptor varies by the variation in the solvent polarity, the nature of the ion, and the strength of the external field. The characteristics of the ion-surface interaction in nonpolar solvents are similar to those observed in vacuum. However, in water, we identified two mechanisms. Soft and polarizable ions preferentially interact with the pi-receptor. On the contrary, two bonded states were found for hard ions. A fully solvated ion, weakly interacting with the receptor at weak field, and a strong pi- complex at strong-field regime were identified.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Physical Chemistry Chemical Physics
ISSN
1463-9076
e-ISSN
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Volume of the periodical
18
Issue of the periodical within the volume
44
Country of publishing house
GB - UNITED KINGDOM
Number of pages
7
Pages from-to
30754-30760
UT code for WoS article
000388492900056
EID of the result in the Scopus database
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