Kinetics and Mechanism of Methanolysis and Cyclization of 1-Acyl-3-(2-halo-5-nitrophenyl)thioureas.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F01%3A00000102" target="_blank" >RIV/00216275:25310/01:00000102 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Kinetics and Mechanism of Methanolysis and Cyclization of 1-Acyl-3-(2-halo-5-nitrophenyl)thioureas.
Original language description
The kinetics of methoxide catalyzed solvolysis of 1-acyl-3-(2-halo-5-nitrophenyl)thioureas and cyclization of fluoro derivatives were studied in methanol at 25 °C. The cyclization involved the substitution of fluorine by sulfur anion of thiourea and produced 2-amino-5-nitrobenzothiazole in two steps.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2001
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Physical Organic Chemistry
ISSN
0894-3230
e-ISSN
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Volume of the periodical
14
Issue of the periodical within the volume
4
Country of publishing house
GB - UNITED KINGDOM
Number of pages
9
Pages from-to
187-195
UT code for WoS article
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EID of the result in the Scopus database
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