The Base-Catalysed Cyclisation of Phenyl N-(2-Hydroxybenzyl)-N-methylcarbamates
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F03%3A00000604" target="_blank" >RIV/00216275:25310/03:00000604 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
The Base-Catalysed Cyclisation of Phenyl N-(2-Hydroxybenzyl)-N-methylcarbamates
Original language description
The rate law of the cyclisation of phenyl N-(2-hydroxybenzyl)-N-methylcarbamates in aqueous solution was identified. The values of rate and equilibrium constants fit Brønsted equations against pK´s corresponding free phenols but system does not conform to the reactivity-selectivity hypothesis. Stepwise mechanism involving a tetrahedral intermediate is ruled out, concerted displacement is probable.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2003
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Organic & Biomolecular Chemistry
ISSN
1477-0520
e-ISSN
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Volume of the periodical
1
Issue of the periodical within the volume
2
Country of publishing house
GB - UNITED KINGDOM
Number of pages
7
Pages from-to
415-421
UT code for WoS article
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EID of the result in the Scopus database
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