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On the reaction pathway in the oxidative dehydrogenation of propane with nitrous oxide over Fe-MFI catalyst

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F05%3A00003194" target="_blank" >RIV/00216275:25310/05:00003194 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    On the reaction pathway in the oxidative dehydrogenation of propane with nitrous oxide over Fe-MFI catalyst

  • Original language description

    Oxidation of propane with N2O over Fe-MFI zeolites with 2500 ppm of iron was investigated in order to analyze the reaction way. A parallel-consecutive reaction scheme was suggested for conversion of propane to propene and propanal and acetone. The reaction intermediates to oxygenate products, which necessarily involves an oxygenation step, should be probably: i) the 1-propyloxy or allyloxy species as precursorof propanal and ii) 2- propyloxy species as precursor of acetone and propene.

  • Czech name

    xx

  • Czech description

    Oxidace propanu pomocí N2O byla studována za účelem zjištění reakčního mechanismu vzniku hlavních produktů. Předpokládaným adsorbovaným intermediátem by mohly být pravděpodobně: i) 1-propyloxy nebo allyloxy částice jako prekurzory propanalu a ii) 2-propyloxy částice jako prekurzor acetonu nebo propenu.

Classification

  • Type

    D - Article in proceedings

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA104%2F03%2F1120" target="_blank" >GA104/03/1120: Catalytic ammoxidation of propane</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2005

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    Proceedings 7th AIZ Conferece on Zeolite Science and Technology joint with 1st Czech-Italian Workshop on Catalysis and Zeolites.

  • ISBN

    88-7458-032-0

  • ISSN

  • e-ISSN

  • Number of pages

    4

  • Pages from-to

    47-50

  • Publisher name

    G. Giordano

  • Place of publication

    Calabria

  • Event location

    Calabria, Italy

  • Event date

    Jun 26, 2005

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article