Structure and solution study of molecular triorganotin compounds containing an N,C,N ligand

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F06%3A00004418" target="_blank" >RIV/00216275:25310/06:00004418 - isvavai.cz</a>

Alternative codes found

RIV/00216208:11310/06:10322

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Structure and solution study of molecular triorganotin compounds containing an N,C,N ligand

Original language description

The triorganotin compounds R-2(NCN)SnX (NCN = C6H3(Me2NCH2)(2-)2,6(-)) containing different polar groups X or substituents R were prepared. The set of organotin compounds Ph-2(NCN)SnX (X = 1 (2), CF3CO2 (3), CH3CO2 (4), Et2NCS2 (5)) was prepared to studythe influence of the polar group X on the character of the Sn-X bond. The effect of substituents R on the character of the Sn-X bond was studied in two additional sets of organotin compounds, R-2(NCN)SnCl (R = Ph (6), Bu (7), Me (8)) and R-2(NCN)SnO2CCH3 (R = Ph (4), Bu (9), Me (10)). The influence of different solvents and temperatures on the presence or absence of covalent Sn-X bonds was studied as well. H-1 and Sn-119 NMR spectroscopy showed the occurrence of dissociation of the Sn-O2CCH3 covalent bond in CD2Cl2 solutions of 4, 9, and 10 at various temperatures (range 300-200 K). The crystal structures of 8 and 10 were studied by X-ray crystallography.

Czech name

Struktura a roztoková studie molekulárních triorganocíničitých sloučenin obsahujícícch N,C,N ligand

Czech description

Byla studována struktura a dynamické vlastnosti molekulárních triorganocíničitých sloučenin obsahujících N,C,N ligand

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2006

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Organometallics

ISSN

0276-7333

e-ISSN

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Volume of the periodical

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Issue of the periodical within the volume

25

Country of publishing house

US - UNITED STATES

Number of pages

6

Pages from-to

148-153

UT code for WoS article

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EID of the result in the Scopus database

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