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Structure and solution study of molecular triorganotin compounds containing an N,C,N ligand

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F06%3A00004418" target="_blank" >RIV/00216275:25310/06:00004418 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216208:11310/06:10322

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Structure and solution study of molecular triorganotin compounds containing an N,C,N ligand

  • Original language description

    The triorganotin compounds R-2(NCN)SnX (NCN = C6H3(Me2NCH2)(2-)2,6(-)) containing different polar groups X or substituents R were prepared. The set of organotin compounds Ph-2(NCN)SnX (X = 1 (2), CF3CO2 (3), CH3CO2 (4), Et2NCS2 (5)) was prepared to studythe influence of the polar group X on the character of the Sn-X bond. The effect of substituents R on the character of the Sn-X bond was studied in two additional sets of organotin compounds, R-2(NCN)SnCl (R = Ph (6), Bu (7), Me (8)) and R-2(NCN)SnO2CCH3 (R = Ph (4), Bu (9), Me (10)). The influence of different solvents and temperatures on the presence or absence of covalent Sn-X bonds was studied as well. H-1 and Sn-119 NMR spectroscopy showed the occurrence of dissociation of the Sn-O2CCH3 covalent bond in CD2Cl2 solutions of 4, 9, and 10 at various temperatures (range 300-200 K). The crystal structures of 8 and 10 were studied by X-ray crystallography.

  • Czech name

    Struktura a roztoková studie molekulárních triorganocíničitých sloučenin obsahujícícch N,C,N ligand

  • Czech description

    Byla studována struktura a dynamické vlastnosti molekulárních triorganocíničitých sloučenin obsahujících N,C,N ligand

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2006

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Organometallics

  • ISSN

    0276-7333

  • e-ISSN

  • Volume of the periodical

  • Issue of the periodical within the volume

    25

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    6

  • Pages from-to

    148-153

  • UT code for WoS article

  • EID of the result in the Scopus database