Decomposition of some Polynitro Arenes Initiated by Heat and Shock. Part II..Several N-(2,4,6-trinitrophenyl)-substituted amino derivatives)

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F06%3A00004583" target="_blank" >RIV/00216275:25310/06:00004583 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Decomposition of some Polynitro Arenes Initiated by Heat and Shock. Part II..Several N-(2,4,6-trinitrophenyl)-substituted amino derivatives)

Original language description

Samples of 2,4,6-trinitroaniline (PAM), 2,4,6-trinitro-N-(2,4,6-trinitrophenyl)aniline (DPA), N,N´-bis(2,4,6-trinitrophenyl)-3,5-dinitropyridine-2,6-diamine (PYX) and N,N?,N??-tris(2,4,6-trinitrophenyl)-1,3,5-triazine-2,4,6-triamine (TPM) were exposed toheat or to shock and then analysed chromatographically (LC?UV and LC/MS). It was found that the main identified decomposition products of these two incomplete initiations are identical for each of the compounds studied. It has been stated that the chemical micro-mechanism of the primary fragmentations of their low-temperature decomposition should be the same as in the case of their initiation by shock, including fragmentation during their detonation transformation.

Czech name

Decomposition of some Polynitro Arenes Initiated by Heat and Shock. Part II..Several N-(2,4,6-trinitrophenyl)-substituted amino derivatives)

Czech description

Samples of 2,4,6-trinitroaniline (PAM), 2,4,6-trinitro-N-(2,4,6-trinitrophenyl)aniline (DPA), N,N´-bis(2,4,6-trinitrophenyl)-3,5-dinitropyridine-2,6-diamine (PYX) and N,N?,N??-tris(2,4,6-trinitrophenyl)-1,3,5-triazine-2,4,6-triamine (TPM) were exposed toheat or to shock and then analysed chromatographically (LC?UV and LC/MS). It was found that the main identified decomposition products of these two incomplete initiations are identical for each of the compounds studied. It has been stated that the chemical micro-mechanism of the primary fragmentations of their low-temperature decomposition should be the same as in the case of their initiation by shock, including fragmentation during their detonation transformation.

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2006

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Hazardous Materials

ISSN

0304-3894

e-ISSN

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Volume of the periodical

neuveden

Issue of the periodical within the volume

137

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

6

Pages from-to

1345-1351

UT code for WoS article

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EID of the result in the Scopus database

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