1-[2-(N,N-dimethylaminomethyl)phenyl]-2,3,4,5-tetraphenylcyclopentadien-1-ol
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F07%3A00006118" target="_blank" >RIV/00216275:25310/07:00006118 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
1-[2-(N,N-dimethylaminomethyl)phenyl]-2,3,4,5-tetraphenylcyclopentadien-1-ol
Original language description
The crystal structure of the title compound, C38H33NO, shows that the OH group interacts with the N atom of the dimethylamino group via an intramolecular hydrogen bond, resulting in the formation of a seven-membered ring. The presence of this interaction, the poor nucleofugal properties of the hydroxy function and the particularly high steric hindrance decrease the ability of the OH group for substitution by other nucleophiles. The crystal packing exhibits no classical intermolecular hydrogen bonds.
Czech name
1-[2-(N,N-dimethylaminomethyl)fenyl]-2,3,4,5-tetraphenylcyclopentadien-1-ol
Czech description
The crystal structure of the title compound, C38H33NO, shows that the OH group interacts with the N atom of the dimethylamino group via an intramolecular hydrogen bond, resulting in the formation of a seven-membered ring. The presence of this interaction, the poor nucleofugal properties of the hydroxy function and the particularly high steric hindrance decrease the ability of the OH group for substitution by other nucleophiles. The crystal packing exhibits no classical intermolecular hydrogen bonds.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2007
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Acta Crystallographica Section E - Structure Reports Online
ISSN
1600-5368
e-ISSN
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Volume of the periodical
63
Issue of the periodical within the volume
N
Country of publishing house
DK - DENMARK
Number of pages
3
Pages from-to
"o577"-"o579"
UT code for WoS article
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EID of the result in the Scopus database
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