Cis-Bistricyanomethanido ? kappa N)tris(2-aminoethyl)amine-kappa N-4)nickel(II)

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F07%3A00006520" target="_blank" >RIV/00216275:25310/07:00006520 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Cis-Bistricyanomethanido ? kappa N)tris(2-aminoethyl)amine-kappa N-4)nickel(II)

Original language description

The crystal structure of the title complex, [Ni(C4N3)(2)(C6H18N4)], is made up of neutral mononuclear [Ni(tren){C(CN)(3)}(2)] units [tren = tris(2-aminoethyl)amine] which are linked through van der Waals interactions and N-H center dot center dot centerdot N hydrogen bonds. The Ni atom has a distorted octahedral coordination environment, bonded to the four tren N atoms [average Ni-N = 2.096 (17) angstrom] and the two cis-positioned C(CN)(3) N atoms [Ni-N = 2.045 (4) and 2.118 (4) angstrom].

Czech name

Cis-Bistricyanomethanido ? kappa N)tris(2-aminoethyl)amine-kappa N-4)nickel(II)

Czech description

The crystal structure of the title complex, [Ni(C4N3)(2)(C6H18N4)], is made up of neutral mononuclear [Ni(tren){C(CN)(3)}(2)] units [tren = tris(2-aminoethyl)amine] which are linked through van der Waals interactions and N-H center dot center dot centerdot N hydrogen bonds. The Ni atom has a distorted octahedral coordination environment, bonded to the four tren N atoms [average Ni-N = 2.096 (17) angstrom] and the two cis-positioned C(CN)(3) N atoms [Ni-N = 2.045 (4) and 2.118 (4) angstrom].

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

<a href="/en/project/LC523" target="_blank" >LC523: Perspective inorganic materials</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2007

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Acta Crystallographica Section E - Structure Reports Online

ISSN

1600-5368

e-ISSN

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Volume of the periodical

63

Issue of the periodical within the volume

63

Country of publishing house

DK - DENMARK

Number of pages

7

Pages from-to

"m2072"

UT code for WoS article

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EID of the result in the Scopus database

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