Synthesis and Structural Study on the Organoantimony(III) and Organobismuth(III) Hydroxides Containing the NCN Pincer Type Ligand

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F09%3A00008331" target="_blank" >RIV/00216275:25310/09:00008331 - isvavai.cz</a>

Result on the web

—

DOI - Digital Object Identifier

—

Result language

angličtina

Original language name

Synthesis and Structural Study on the Organoantimony(III) and Organobismuth(III) Hydroxides Containing the NCN Pincer Type Ligand

Original language description

The reactions of the dimeric organoantimony(III) oxide containing the NCN chelating ligand L, with the trifluoroacetic and the trifluoromethanesulfonic acid gave unprecedented organoantimony hydroxides LSb(OH)(X) (X = triflate or trifluoroacetate). On the other hand, analogous reaction with the acetic acid and the tetrafluroboric acid led to a polar group exchange. By an analogy, the reaction of the organobismuth oxide gave the bismuth acetate in the reaction with the acetic acid, but the hydroxide LBi(OH)(triflate) was obtained, when the trifluoromethanesulfonic acid was used.

Czech name

—

Czech description

—

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

—

Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2009

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Organometallics

ISSN

0276-7333

e-ISSN

—

Volume of the periodical

28

Issue of the periodical within the volume

18

Country of publishing house

US - UNITED STATES

Number of pages

7

Pages from-to

—

UT code for WoS article

—

EID of the result in the Scopus database

—