Spontaneous transformation of TATP to DADP(full paper)

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F09%3A00008652" target="_blank" >RIV/00216275:25310/09:00008652 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Spontaneous transformation of TATP to DADP(full paper)

Original language description

TATP, prepared in the presence of catalysts methanesulfonic, perchloric or sulfuric acid, has been found to undergo spontaneously transformation to DADP. However, no transformation occurs if TATP is purified or prepared involving catalyst hydrochloric acid and just traces of DADP in samples were observed in samples of TATP when nitric acid and tin(IV) chloride were used. The rate of transformation depends on temperature of aging and on molar ratio of catalyst to acetone (nc/na) used during preparation of TATP. The faster rate of the transformation was observed at high temperatures and higher molar ratio nc/na

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2009

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Propellants Explosives Pyrotechnics

ISSN

0721-3115

e-ISSN

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Volume of the periodical

34

Issue of the periodical within the volume

6

Country of publishing house

DE - GERMANY

Number of pages

5

Pages from-to

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UT code for WoS article

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EID of the result in the Scopus database

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