The Structure of the Product Formed by Condensation of Malononitrile with Dialkyl Acetone-1,3-dicarboxylates
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F10%3A39881311" target="_blank" >RIV/00216275:25310/10:39881311 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
The Structure of the Product Formed by Condensation of Malononitrile with Dialkyl Acetone-1,3-dicarboxylates
Original language description
By the condensation of malononitrile (1) with dialkyl acetone-1,3-dicarboxylates 2a, b alkyl (3-cyano-6-alkoxy-2-oxo-1,2-dihydropyridin-4-yl)acetates 6a, b are formed in contrast to an earlier report according to which diethyl 3-(dicyanomethylene)glutarate 3b was obtained in the reaction of 1 and 2a. Compounds 6a, b were transformed with DMFDMA into the corresponding (E)-alkyl 2-(3-cyano-6-alkoxy-2-oxo-1,2-dihydropyridin-4-yl)-3-(dimethylamino)propenoates 7a, b. The structures of 6a and 7a were confirmed by X-ray structural analysis.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Zeitschrift für Naturforschung Section B - A Journal of Chemical Sciences
ISSN
0932-0776
e-ISSN
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Volume of the periodical
65
Issue of the periodical within the volume
7
Country of publishing house
DE - GERMANY
Number of pages
4
Pages from-to
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UT code for WoS article
000280446000006
EID of the result in the Scopus database
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