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Raman studies and some physical properties of selected (PbO)x(Nb2O5)y(TeO2)1-x-y glasses

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F10%3A39881473" target="_blank" >RIV/00216275:25310/10:39881473 - isvavai.cz</a>

  • Alternative codes found

    RIV/61389013:_____/10:00347231

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Raman studies and some physical properties of selected (PbO)x(Nb2O5)y(TeO2)1-x-y glasses

  • Original language description

    Selected Nb2O5-TeO2, PbO-Nb2O5-TeO2 and PbO-TeO2 glasses were prepared from very pure oxides.The glass-transition temperature increased from 281 to 411 °C with an increase in Nb2O5 content and,simultaneously, the coefficient of thermal expansion decreased from 21 to 11 ppm/°C. Raman scattering measurements indicated that TeO4 trigonal bipyramids, TeO3+1, TeO3 trigonal unit and NbO6 octahedra were the basic structural units of Nb2O5-TeO2 and PbO-Nb2O5-TeO2 glasses. The optical band gap was determined inthe region 3.39-3.60 eV and the coefficient of the temperature dependence of the optical gap for the temperatures between 30 and 250 °C in the region 4.1 x 10(-4) - 6.8 x 10(-4) eV/K was found. Non-linear refractive index of the studied glasses was estimated from the optical gap values at around 0.85 x 10-11 esu.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    JH - Ceramics, fire-proof materials and glass

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2010

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Optical Materials

  • ISSN

    0925-3467

  • e-ISSN

  • Volume of the periodical

    32

  • Issue of the periodical within the volume

    9

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    6

  • Pages from-to

  • UT code for WoS article

    000279620900021

  • EID of the result in the Scopus database