Molybdenum complexes containing substituted cyclopenta[l]phenanthrenyl ligand

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F10%3A39882987" target="_blank" >RIV/00216275:25310/10:39882987 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Molybdenum complexes containing substituted cyclopenta[l]phenanthrenyl ligand
Original language description
The synthesis of new cyclopenta[l]phenanthrenyl complexes [(C17H10Me)(C3H5)Mo(CO)2] and [(C17H9(COOMe)N(CH2)4)(C3H5)Mo(CO)2] is described. Although these compounds are structural analogues their reactivity is different. Protonation of [(C17H10Me)(C3H5)Mo(CO)2] gives a stable ionic compound [(C17H10Me)Mo(CO)2(NCMe)2][BF4] while its analogue containing both tertiary amino and carboxylic ester groups [(C17H9(COOMe)N(CH2)4)(C3H5)Mo(CO)2] decomposes under the same conditions. [(C17H10Me)Mo(CO)2(NCMe)2][BF4]reacts with cyclopentadiene to give a stable complex [(C5H6)(C17H10Me)Mo(CO)2][BF4] that was successfully oxidized to the Mo(IV) dicationic compound [(C5H5)(C17H10Me)Mo(CO)2][Br][BF4].
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GP203%2F09%2FP100" target="_blank" >GP203/09/P100: Ring-functionalized vanadocene and molybdenocene complexes</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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