2D-supramolecular layers built of antiferromagnetically coupled [Cu(x-O(2)Nbz)(2)(denia)(1)(H(2)O)(1)](n) 1D-polymers with R(2)(2)(10) and R(2)(2)(12) supramolecular synthons

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F11%3A39892429" target="_blank" >RIV/00216275:25310/11:39892429 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1016/j.poly.2010.09.034" target="_blank" >http://dx.doi.org/10.1016/j.poly.2010.09.034</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.poly.2010.09.034" target="_blank" >10.1016/j.poly.2010.09.034</a>

Result language

angličtina

Original language name

2D-supramolecular layers built of antiferromagnetically coupled [Cu(x-O(2)Nbz)(2)(denia)(1)(H(2)O)(1)](n) 1D-polymers with R(2)(2)(10) and R(2)(2)(12) supramolecular synthons

Original language description

Polymeric complexes of composition [Cu(3.5-(O(2)N)(2)bz)(2)(mu-denia)(1)(H(2)O)(1)](n) (1) (3,5-(O(2)N)(2)bz = 3,5-dinitrobenzoate) and [(Cux-O(2)Nbz)(2)(mu-denia)(1)(H(2)O)(1)] x = 3 (2), x = 4 (3) (denia = diethylnicotinamide, and x-O(2)Nbz = 3- or 4-nitrobenzoate) have been prepared, characterized by elemental analysis and studied by electronic, infrared and EPR spectra, as well as by magnetization measurements over the temperature range 1.8-300 K, and their structures have been solved. The basic structure unit of all complexes consists of Cu(II) atom monodentately coordinated by the pair of nitrobenzoato anions in trans-positions together with water and diethylnicotinamide molecules, forming nearly tetragonal basal plane of the coordination polyhedron. The axial position of tetragonal-pyramidal coordination polyhedron is occupied by diethylnicotinamide oxygen atom of neighbouring structural unit thus forming spiral polymeric molecule parallel to b-axis. The neighbouring polymeric m

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2011

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Polyhedron

ISSN

0277-5387

e-ISSN

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Volume of the periodical

30

Issue of the periodical within the volume

1

Country of publishing house

GB - UNITED KINGDOM

Number of pages

7

Pages from-to

86-92

UT code for WoS article

000287059400013

EID of the result in the Scopus database

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