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Dichloridobis{2-[(dimethylamino)methyl]phenyl}bis{2-[(dimethylazaniumyl)methyl]phenyl} di-mý-hydroxido-di-mý(3)-oxido-tertaphenyltetratin(IV) dichloride deuterochloroform decasolvate.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F11%3A39892432" target="_blank" >RIV/00216275:25310/11:39892432 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1107/S1600536811048872" target="_blank" >http://dx.doi.org/10.1107/S1600536811048872</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1107/S1600536811048872" target="_blank" >10.1107/S1600536811048872</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Dichloridobis{2-[(dimethylamino)methyl]phenyl}bis{2-[(dimethylazaniumyl)methyl]phenyl} di-mý-hydroxido-di-mý(3)-oxido-tertaphenyltetratin(IV) dichloride deuterochloroform decasolvate.

  • Original language description

    The ladder-like structure of the tetranuclear title compound, [Sn(4)(C(6)H(5))(4)Cl(2)O(2)(OH)(2)(C(9)H(13)N)(2)(C(9)H(12)N)(2)]Cl(2)?10CDCl(3), consists of two five- and two six-coordinated Sn(IV) atoms bridged by oxide or hydroxide groups. The chelating ligands reveal rather strong Sn-N bonds [2.517(4)?], but the protonated dimethylamino groups in the periphery of the complex show no interaction with the metal atoms. The complex cation is located on an inversion centre. The chloride anion is linked tothe complex molecule by strong intramolecular O-H???Cl and N-H???Cl hydrogen bonds. Five independent deuterochloroform accompany the complex, two of them are disordered [occupancy ratios 0.63 (2):0.27 (2) and 0.60 (2):0.40 (2)].

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GPP207%2F10%2FP092" target="_blank" >GPP207/10/P092: Activation of Small Molecules and Unsaturaturated Systems by Tin Compounds</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2011

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Acta Crystallographica Section E - Structure Reports Online

  • ISSN

    1600-5368

  • e-ISSN

  • Volume of the periodical

    67

  • Issue of the periodical within the volume

  • Country of publishing house

    DK - DENMARK

  • Number of pages

    2

  • Pages from-to

    "m1890"-"m1891"

  • UT code for WoS article

    000298794900001

  • EID of the result in the Scopus database