Dichloridobis{2-[(dimethylamino)methyl]phenyl}bis{2-[(dimethylazaniumyl)methyl]phenyl} di-mý-hydroxido-di-mý(3)-oxido-tertaphenyltetratin(IV) dichloride deuterochloroform decasolvate.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F11%3A39892432" target="_blank" >RIV/00216275:25310/11:39892432 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1107/S1600536811048872" target="_blank" >http://dx.doi.org/10.1107/S1600536811048872</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1107/S1600536811048872" target="_blank" >10.1107/S1600536811048872</a>
Alternative languages
Result language
angličtina
Original language name
Dichloridobis{2-[(dimethylamino)methyl]phenyl}bis{2-[(dimethylazaniumyl)methyl]phenyl} di-mý-hydroxido-di-mý(3)-oxido-tertaphenyltetratin(IV) dichloride deuterochloroform decasolvate.
Original language description
The ladder-like structure of the tetranuclear title compound, [Sn(4)(C(6)H(5))(4)Cl(2)O(2)(OH)(2)(C(9)H(13)N)(2)(C(9)H(12)N)(2)]Cl(2)?10CDCl(3), consists of two five- and two six-coordinated Sn(IV) atoms bridged by oxide or hydroxide groups. The chelating ligands reveal rather strong Sn-N bonds [2.517(4)?], but the protonated dimethylamino groups in the periphery of the complex show no interaction with the metal atoms. The complex cation is located on an inversion centre. The chloride anion is linked tothe complex molecule by strong intramolecular O-H???Cl and N-H???Cl hydrogen bonds. Five independent deuterochloroform accompany the complex, two of them are disordered [occupancy ratios 0.63 (2):0.27 (2) and 0.60 (2):0.40 (2)].
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GPP207%2F10%2FP092" target="_blank" >GPP207/10/P092: Activation of Small Molecules and Unsaturaturated Systems by Tin Compounds</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Acta Crystallographica Section E - Structure Reports Online
ISSN
1600-5368
e-ISSN
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Volume of the periodical
67
Issue of the periodical within the volume
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Country of publishing house
DK - DENMARK
Number of pages
2
Pages from-to
"m1890"-"m1891"
UT code for WoS article
000298794900001
EID of the result in the Scopus database
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