Method Validation for the Determination of Propellant Components by Soxhlet Extraction and Gas Chromatography/Mass Spectrometry

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F11%3A39892558" target="_blank" >RIV/00216275:25310/11:39892558 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1002/jssc.201100279" target="_blank" >http://dx.doi.org/10.1002/jssc.201100279</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/jssc.201100279" target="_blank" >10.1002/jssc.201100279</a>

Result language

angličtina

Original language name

Method Validation for the Determination of Propellant Components by Soxhlet Extraction and Gas Chromatography/Mass Spectrometry

Original language description

A fast, sensitive, and accurate GC/MS method for the quantification of aliphatic nitroesters (ethylene glycol dinitrate, nitroglycerin, and triethylene glycol dinitrate) and aromatic amines (diphenylamine, 2-nitrodiphenylamine, and triphenylamine) in propellants was developed and validated. This method comprises a Soxhlet extraction step with dichloromethane, followed by separation on a capillary column MDN-5. Ionization of the analytes is carried out using electron ionization. The limit of quantification of the method was 1% w/w for aliphatic nitroesters and 0.1% w/w for aromatic amines (diphenylamine and triphenylamine). Values of repeatability and reproducibility for analyzed compounds were smaller than values of the maximum allowed tolerances of the Horwitz-equation RSD(max) and 2/3 RSD(max).

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CB - Analytical chemistry, separation

OECD FORD branch

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Project

<a href="/en/project/FR-TI1%2F131" target="_blank" >FR-TI1/131: *Energetic Substances and Their Precursors Identification and Determination Methods Development</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2011

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Separation Science

ISSN

1615-9306

e-ISSN

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Volume of the periodical

34

Issue of the periodical within the volume

18

Country of publishing house

DE - GERMANY

Number of pages

6

Pages from-to

2405-2410

UT code for WoS article

000295968000006

EID of the result in the Scopus database

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