Synthesis and crystal structure of two copper(II) complexes with coordinated decavanadate ion

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F12%3A39895376" target="_blank" >RIV/00216275:25310/12:39895376 - isvavai.cz</a>
Result on the web
<a href="http://www.sciencedirect.com/science/article/pii/S0277538711006838" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0277538711006838</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.poly.2011.10.042" target="_blank" >10.1016/j.poly.2011.10.042</a>

Result language
angličtina
Original language name
Synthesis and crystal structure of two copper(II) complexes with coordinated decavanadate ion
Original language description
Two new compounds containing decavanadate ions coordinated to copper centers, (2-hepH(+))(2)[{Cu (H2O)(2)(O,N-2-hep)}(2)V10O28]center dot 6H(2)O (2-hepH(+) = 2-(2-hydroxyethyl)pyridinium; 2-hep = 2-(2-hydroxyethyl) pyridine) (1), [{Cu(2-amp)(2)(H2O)}(2)H2V10O28]center dot 4H(2)O (amp = 2-(aminomethyl)pyridine) (2), have been prepared and characterized by elemental analyses and IR spectroscopy. The structure of 1 consists of trinuclear units [{Cu(H2O)(2)(O,N-2-hep)}(2)V10O28](2-), 2-hepH(+) cations and molecules of water of crystallization. A trinuclear unit [{Cu(2-amp)(2)(H2O)}(2)H2V10O28] is a principal part also in the structure of 2, but the bonds of decavanadate group to the copper complexes are much weaker than in 1.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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