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Nucleation and crystallization of an As2Se3 undercooled melt

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F12%3A39895506" target="_blank" >RIV/00216275:25310/12:39895506 - isvavai.cz</a>

  • Result on the web

    <a href="http://www.ingentaconnect.com/content/sgt/pcg/2012/00000053/00000006/art00008" target="_blank" >http://www.ingentaconnect.com/content/sgt/pcg/2012/00000053/00000006/art00008</a>

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Nucleation and crystallization of an As2Se3 undercooled melt

  • Original language description

    The isothermal nucleation of an As2Se3 undercooled melt followed by crystallization and consequent melting was measured by DSC using a constant heating rate. The melting enthalpy was used to quantify the degree of conversion, a. Nonlinear regression analysis of the dependence of conversion on isothermal nucleation temperature and time was performed on the basis of classical nucleation theory assuming normal 3D growth. The parameters for the temperature dependence of nucleation rate and growth rate weredetermined by a three step process. First the simple parabolic model was used to estimate the maximum and the width of rate-temperature curve. Then the obtained parabolic curves were fitted by theoretical ones. In the third step the parameters obtained in the previous steps were used for nonlinear regression analysis of the experimental data. The kinetic barrier of crystal growth was found to be in agreement with the activation energy for viscous flow.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    JH - Ceramics, fire-proof materials and glass

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2012

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Physics and Chemistry of Glasses: European Journal of Glass Science and Technology Part B

  • ISSN

    0031-9090

  • e-ISSN

  • Volume of the periodical

    53

  • Issue of the periodical within the volume

    6

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    5

  • Pages from-to

    289-293

  • UT code for WoS article

    000312920500008

  • EID of the result in the Scopus database