Synthesis and Cytostatic activity of Pt(II) complexes of intramolecularly coordinated phosphine and stibine ligands
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F12%3A39895562" target="_blank" >RIV/00216275:25310/12:39895562 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11150/12:10124795
Result on the web
<a href="http://dx.doi.org/10.1002/aoc.2845" target="_blank" >http://dx.doi.org/10.1002/aoc.2845</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/aoc.2845" target="_blank" >10.1002/aoc.2845</a>
Alternative languages
Result language
angličtina
Original language name
Synthesis and Cytostatic activity of Pt(II) complexes of intramolecularly coordinated phosphine and stibine ligands
Original language description
The intramolecularly coordinated phosphine and stibine ligands L1PPh2 (1), L2PPh2 (2) and L2SbPh2 (3) containing Y,C,Y-chelating ligands, L1?=?2,6-(tBuOCH2)2C6H4- and L2?=?2,6-(Me2NCH2)2C6H4-, were prepared and characterized. The treatment of these ligands 13 with PtCl2 yielded complexes trans-{[2,6-(tBuOCH2)2C6H3]PPh2}2PtCl2 (4), cis-{[2,6-(Me2NCH2)2C6H3]PPh2}PtCl2 (5), and cis-{[2,6-(Me2NCH2)2C6H3]SbPh2}PtCl2 (6) as the result of different ability of the starting compounds 13 to complex platinum centre. Compounds 16 were characterized by 1H, 13C and 31P NMR spectroscopy and electrospray ionization mass spectrometry, and molecular structures of 36 were determined by X-ray diffraction analysis. The substitution reactions of complexes 46 were also studied. The reaction of 5 and 6 with NaI yielded complexes {[2,6-(Me2NCH2)2C6H3]PPh2}PtI2 (7) and {[2,6-(Me2NCH2)2C6H3]SbPh2}PtI2 (8), while the same reaction of 4 with NaI did not proceed. As the compounds 7 and 8 structurally resemble cispl
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GAP207%2F10%2F0215" target="_blank" >GAP207/10/0215: Structure, Properties and the Use of C,N-, Y,C,Y-chelated Organometallic and Related Metal Complexes</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Applied Organometallic Chemistry
ISSN
0268-2605
e-ISSN
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Volume of the periodical
26
Issue of the periodical within the volume
5
Country of publishing house
GB - UNITED KINGDOM
Number of pages
9
Pages from-to
237-245
UT code for WoS article
000303042800006
EID of the result in the Scopus database
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