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Mg/Al MIXED OXIDES: PREPARATION, PROPERTIES AND CATALYTIC ACTIVITY IN TRANSESTERIFICATION OF RAPESEED OIL

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F12%3A39895749" target="_blank" >RIV/00216275:25310/12:39895749 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Mg/Al MIXED OXIDES: PREPARATION, PROPERTIES AND CATALYTIC ACTIVITY IN TRANSESTERIFICATION OF RAPESEED OIL

  • Original language description

    This paper reviews the preparation, physicochemical properties and application of Mg/Al mixed oxides. Attention is focused on the activity of Mg/Al mixed oxides in transesterification of rapeseed oil. The mixed oxides were prepared from hydrotalcites bycalcination and were characterized by XRD, FTIR and AAS. The aim of work was to study the effect of Mg/Al mixed oxides properties such as Mg/Al mass ratio (2-4), the temperature of calcination (450-1000 °C), time of calcination (4-17 h) and post-treatment rehydration of mixed oxides on the activity of Mg/Al catalysts in the transesterification reaction. The results show that the highest catalytic activity was observed for Mg/Al catalysts with Mg/Al mass ratio of 3, calcination temperature of 450 °C, time of calcination of 8 hours and rehydration by water. The leaching of magnesium to liquid phase was also determined and was always less than 0.1 wt. % - the catalyst was stable.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GAP106%2F11%2F0773" target="_blank" >GAP106/11/0773: Analysis of the structure/activity relationship of acid-base heterogeneous catalysts in esterification and transesterification reactions</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2012

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Scientific Papers of the University of Pardubice, Series A, Faculty of Chemical Technology

  • ISSN

    1211-5541

  • e-ISSN

  • Volume of the periodical

    18

  • Issue of the periodical within the volume

    prosinec

  • Country of publishing house

    CZ - CZECH REPUBLIC

  • Number of pages

    14

  • Pages from-to

    91-104

  • UT code for WoS article

  • EID of the result in the Scopus database