Structure of beta-diketiminates and beta-aminoketones made from anisidines or chloroanilines: tin and lithium complexes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F12%3A39895764" target="_blank" >RIV/00216275:25310/12:39895764 - isvavai.cz</a>
Alternative codes found
RIV/61388955:_____/12:00380851
Result on the web
<a href="http://www.degruyter.com/view/j/mgmc.2012.35.issue-1-2/mgmc-2012-0002/mgmc-2012-0002.xml" target="_blank" >http://www.degruyter.com/view/j/mgmc.2012.35.issue-1-2/mgmc-2012-0002/mgmc-2012-0002.xml</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1515/mgmc-2012-0002" target="_blank" >10.1515/mgmc-2012-0002</a>
Alternative languages
Result language
angličtina
Original language name
Structure of beta-diketiminates and beta-aminoketones made from anisidines or chloroanilines: tin and lithium complexes
Original language description
Three series of methoxyphenyl substituted beta-diketiminate and beta-enaminoketonate and chlorophenyl beta-enaminoketonate ligands were prepared and studied by IR, H-1 and C-13 NMR spectroscopy in solution and X-ray diffraction techniques in solid state.The crystal structures of [2-(MeO)C6H4]N=(H)-CCH(H)C[2-(MeO)C6H4]NH.HCl, [2-(MeO)C6H4]N=(H)CCH(H)C[2-(MeO)C6H4]NH, [4-(MeO)C6H4]N=(H)CCH-(H) C[4-(MeO)C6H4]NH, [4-ClC6H4]N(H)(Me)CCH(Me)C=O, [2-(MeO)C6H4]N=(Me)CCH(Me)C[2-(MeO)C6H4]NH and 7-methoxy-2,4-dimethylquinoline-toluenesulfonyl acid adduct as ligands, their precursors and a byproduct isolated during the synthesis of [3-(MeO)C6H4]N(H)(Me)CCH(Me)C=O were determined. One of the ligands the meta-methoxyphenyl substituted beta-enaminone has been treated with n-butyllithium to give {[3-ClC6H4]N(Me)CCH(Me)C=O}Li which reveals tetrameric structure in the solid state. Further reactions of this lithium complex with tri-and diorganotin(IV) chlorides and hydride give appropriate organotin(IV)
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GAP106%2F10%2F0924" target="_blank" >GAP106/10/0924: The electron deficient transition metal complexes containing bifunctional beta-diketiminate and cyclopentadienyl ligands ? design of new catalysts.</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Main Group Metal Chemistry
ISSN
0334-7575
e-ISSN
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Volume of the periodical
35
Issue of the periodical within the volume
1-2
Country of publishing house
GB - UNITED KINGDOM
Number of pages
15
Pages from-to
13-27
UT code for WoS article
000304082500002
EID of the result in the Scopus database
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