Quest for lithium amidinates containing adjacent amino donor group at the central carbon atom

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F13%3A39896220" target="_blank" >RIV/00216275:25310/13:39896220 - isvavai.cz</a>
Result on the web
<a href="http://www.sciencedirect.com/science/article/pii/S0022328X13005743" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0022328X13005743</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jorganchem.2013.07.067" target="_blank" >10.1016/j.jorganchem.2013.07.067</a>

Result language
angličtina
Original language name
Quest for lithium amidinates containing adjacent amino donor group at the central carbon atom
Original language description
Lithium amidinate complexes bearing different peripheral substituents on both nitrogen atoms (iPr and Dipp (2,6-di(isopropyl)phenyl-) and pendant, potentially coordinating group originated from the 2-(N,N-dimethylaminomethyl)phenyl moiety, at the centralcarbon atom were prepared by addition of the 2(N,N-dimethylaminomethyl)phenyllithium to the appropriate carbodiimides. The structure of the isopropyl group substituted lithium amidinates is dimeric with bidentate amidinate unit and four-coordinated lithium atom. On contrary the Dipp group substituted lithium amidinate is monomeric with trigonal planar geometry of the lithium atom, monodentately bound amidinate unit and coordinated pendant arm.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GAP207%2F12%2F0223" target="_blank" >GAP207/12/0223: Hybrid ligands for low valent metal centres stabilization/specific activation.</a><br>
Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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