Epoxy/poly(epsilon-caprolactone) nanocomposites: Effect of transformations of structure on crystallization

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F13%3A39896228" target="_blank" >RIV/00216275:25310/13:39896228 - isvavai.cz</a>
Alternative codes found
RIV/61389013:_____/13:00395433
Result on the web
<a href="http://onlinelibrary.wiley.com/doi/10.1002/app.39536/abstract;jsessionid=9936E12358B05FAC0A7E18D99620C6E1.f04t04" target="_blank" >http://onlinelibrary.wiley.com/doi/10.1002/app.39536/abstract;jsessionid=9936E12358B05FAC0A7E18D99620C6E1.f04t04</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/app.39536" target="_blank" >10.1002/app.39536</a>

Result language
angličtina
Original language name
Epoxy/poly(epsilon-caprolactone) nanocomposites: Effect of transformations of structure on crystallization
Original language description
The influence of morphology of the epoxy/poly(-caprolactone) (PCL) system and corresponding nanocomposites with organophilized layered silicate on PCL crystallization was studied by differential scanning calorimetry, scanning, and transmission electron microscopy. The results obtained indicate a significant affecting of nonisothermal PCL crystallization by phase morphology brought about by the reaction-induced phase separation (RIPS) influenced either by various nanoclay contents or the epoxy/PCL ratio.Dispersed morphology of PCL matrix with epoxy globules induces crystallization at higher temperatures. The inverse dispersed morphology of epoxy matrix with PCL inclusions causes crystallization at lower temperature. The co-continuous morphology inducescrystallization in both steps. Rate of the second crystallization step is substantially higher than that in the first step. No nucleation effect has been found in the nanocomposites with the added nanofiller. Multicomponent samples show
Czech name
—
Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CD - Macromolecular chemistry
OECD FORD branch
—

Project
<a href="/en/project/IAA200500904" target="_blank" >IAA200500904: Optimizing structure and properties of multiphase thermosets using self-assembled nanofiller-based inclusions</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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